Method of converting petroleum and like oils



Sept. 14, 1943. "r. P. ISIMPSQN ETAL METflOD OF CONVERTING PETROLEUM AND LIKE OILS Original Fi led Sept. '1, 1957 4 Sheets-Sheet 1 gwuvwbod Mama: EJ240500,

MA. Jr

Sept. 14, 1943. T. P. SIMPSON ETAL METHOD OF CONVERTING PETROLEUM AND LIKE OILS Origixial Filed Sept. 1 1937 4 Sheefs-Sheet 2 P r. P. SIMPSON ETAL METHOD OF CONVERTING PETROLEUM AND LIKE OILS Origin'al Filed Sept. 1, 1937 4 Sheets-Sheet 5 Sept. 14,1943. 1=. P. SIMPSON :rm. 2,329,653

METHOD OF CONVERTING PETROLEUM AND LIKE OILS Original Filed Sept. 1, 1957 4 Sheets-Sheet 4- cm'mcr Miss non smas- I 1 o I 1 film/VT H0 Patented Sept. 14, 1943 METHOD OFCONVERTING PETROLEUM AND LIKE OILS Thomas P. Simpson, John W. Payne, and John A. Crowley, J12, 'Woodbury, and Clark's. Teitsworth, Plainfield, N. J., assignors to Socony- Vacuum Oil Company, Incorporated, New York, N. Y., a corporation of New York Original application September 1, .1937, Serial No;

162,070. Divided and this application Decembet 7, 1939, Serial No. 308,058

18 Claims.

'a contact mass, including regeneration of the contact mass.

This application is a division of our copending application Serial Number 162,070, filed September l, 1937, now Patent No. 2,185,930 and is directed to a process of the general type disclosed and claimed in our copending application Serial Number 162,069, filed September 1, 1937,

now Patent No. 2,185,929 which invention is di-,

rectedto catalytic processes in general, andmay be carried out in an apparatus such as disclosed and claimed in our copending application Serial Number 162,068 filed September 1, 1937, now Patent No. 2,185,928. The process herein disclosed and claimed was devised-to afford a method particularly adapted for carrying out processes of catalytic conversion of hydrocarbon oils and may be carried out in an apparatus such as, for instance, is disclosed in our copending case Serial Number 162,071, filed September 1, 1937, now Patent No. 2,185,931. Our copending applica tions, Serial Numbers 162,540, new Patent No. 2,209,040, 162,541 and 162,542, now .Patent No. 2,222,304, filed September 4, 1937, are likewise directed to processes and apparatus for catalytic conversion of the same general type as that of said Serial Numbers 162,068 and 162,069. However, among other features these three former cases are directed to novel features of reversal of fluid flow, continuousflow, of catalytic material and controlling temperature of catalytic material respectively.

Many types of conversions of hydrocarbons into materials of different properties, physical and/ or chemical, or carried on hydrocarbons, frequently in vapor form and .at high temperature, of particles which themselves have a catalytic effect, or which are impregnated with or act as a support for material of a catalytic nature appropriate to the result desired. Such operations may contemplate, for example, the conversion of hydrocarbons of high boiling point into hydrocarbons of lower boiling ing in the vapor phase. Another common operation is the polymerization, under c'atalytic conditions, of light or gaseous hydrocarbons to form by contacting the highly useful nature.

' principle have been developed. I One type of cata-' tial oxidation or similar conversions of hydrocarbons under similar conditions. Some operations carried out wholly or partially in'liquid phase present similar problems. The method'of operation herein disclosed is applicable to such conversions in general. This method is equally applicable to both endothermic and exothermic reactions. "Of these operations, the vapor phase cracking of hydrocarbons to produce gasoline is typical, and this specification will hereinafter discuss such operation as exemplary'without, however, intending to be limited thereby or thereto except by such limitations as are'stated in the claims.

It is known that hydrocarbon oils of high boiling pointjwhen properly contacted in vapor phase with a catalytic material of proper kind are converted into oils of lower boiling point of Processes based upon this lyst which has been used is composed of granular particles of. the nature of clay, which may or may not have deposited thereon or thereinoth'er materials of a catalytic nature. Mineral oil fractions of the nature of gas oil may, for example, be conducted at temperatures of say 810 F. or higher over a catalytic mass composed of cylindrical particles of catalytic (activated), clay about 2 /2 mm. diameter by 4 mm. 1ength, reisulting in substantial conversion into gasoline.

In most prior proposed petroleum catalytic proc,-.

esses, petroleum vapors are merely passed into a bodyv of catalyst of large orsmall depth and are" caused to flow through the catalyst in more or with a contact mass composed pointby catalytic crackhydrocarbons of higher boiling point. Other,

operations of this same general nature are catalytic dehydrogenation, desulphurizing, parless broadcast manner. In such operations considerable jdifliculties are had with channeling,

short circuiting, and the like, whereby some portions of the catalyst volume are never reached by a proper amount of reaction mixture and,

othersv are consistently reached by too much reaction mixture, resulting in erratic and improper treatment. Also, localized reactions cause localized deposits of reaction products, and during regeneration of the catalyst, cause localized regeneration, which is unsatisfactory. It has been catalytic material in furnace.

proposed to place tubes through which oil is passed but thisis not suitable for reactions where thermal cracking is' not desired, as well as for other reasons. It has also been proposed to distill oil and then pass vapors from the distillation operation through catalyst containing tubes submergedin This the body of oil undergoing distillation. operation is not useful, having many objections,

including limitations of temperature and heat ducting reactions upon petroleum in the presence i of a contact mass, including regeneration of said mass, which is effective in producing the desired results, avoids the various objections stated above, combines high rates of charge With high yields of desirable product, is capable of efficient and uniform use of all portions of the catalyst mass, is capable of effecting rapid, complete, uniform and readily controlled regeneration of catalyst in situ, is economical in operation as well as simple and flexible, and is capable of being housed in equipment of economical design and capable of easy maintenance.

This invention embodies the principle, Which we have established, that the hydrocarbon reactions contemplated herein are best carried on in a catalyst path which is of relatively great length in the direction of flow of reaction material and relatively quite thin in at least one direction transverse to the direction of flow of reaction material, if the rate of reaction in the various proportions of that path be properly controlled, and that the necessary control may be accomplished by properly forming the catalyst paths and placing them adjacent paths for a heat exchange medium, establishing the proper relation between such paths and the contents thereof, and continuously and positively circulating a heattransfer medium in proper heat exchange relationship with the catalyst. The reaction method practiced in accordance with this invention leaves the spent catalyst in a condition well fitted for easy and uniform regeneration, and with the regeneration also conducted in accordance with the invention, a unitary conversion process of great utility results therefrom.

Effective control of conditions throughout the catalyst'or contact mass is an important element of the invention. This invention provides a method for conducting the reactions referred to herein, including regeneration of contact material in situ, by means of which such effective control of conditions is accomplished, thereby attaining correspondingly effective operation. Proper flow of reactants through the contact mass is effected, so that all portions of the fluid traversing the mass receivev substantially iden-' tical treatment, thus promoting uniformity, of

reaction and uniformity of quality ,in'th'e reac This is accomplished by providing tion product. a plurality of long unit paths of flow, having at least one relatively short cross-dimension, through the contact mass, wherein the variation in length of paths travelled by different portions of the fluid flowing through the mass is small.

In one embodiment, provision may be made for by-passing virtually any desired section of each unit path so that, in case the path becomes blocked at some point, as for instance by accumulated'fines, unburned carbon, or the like, instead of the entire path becoming useless or impaired, the particular point in the path which is blocked is by-passed and substantially full use of'the contact mass throughout the remainder of the path is secured. Various embodiments aocomplishing this are illustrated in the drawin s and described herein.

Effective temperature control throughout the contact mass is accomplished. Heat transfer positive circulation at relatively high velocity of elements are associated with the respective catalyst paths, and every part of the contact mass lies sufficiently close to a heat transfer element to insure notable uniformity of temperature throughout the entire contact mass. Heat can be put into the contact mass or removed from it as desired. Heat distribution between different portions of the catalyst mass is effected. This means for effecting this transfer of heat and control of temperature preferably involves heat transfer medium through the heat transfer elements. A high boiling point liquid having a relatively high unit volume heat absorption capacity per degree temperature change is preferred, although fluid media such as vapors, steam, gas, air, or the like, may be used. Means for heating or cooling the circulating heat transfer medium are provided.

A small volume of heat transfer medium relative to volume of contact mass is used. This conserves size and cost of apparatus, with a high proportion of total apparatus volume occupied by contact mass. It givesflexibility to the op: eration of the apparatus, because the entire volume of heat transfer medium in the apparatus. is renewed at short intervals by the recirculation, with corresponding quick response of the apparatus to the'temper'ature control effected by adding heat to or abstracting heat from the recirculating body of heat transfer medium. This is important in practically all operations and particularly in operations where reactions,

are conducted in sequence at different tempera ture levels, where temperature must be built up to initiate a reaction, and the like. A large. area of heat transfer surface in contact with the catalyst mass relative to volume of heat transfer medium in the apparatus is used. This is important in making possible the use of a small volume of heat exchange medium with its attendant flexibility of operation just mentioned. These features result in advantages in design, constructionand cost of apparatus; e. g., in most forms of commercial apparatus, fewer heat trans-.

fer fluid passages are required, Widerspacing of these elements is possible, stronger headers are made possible thereby, or thinner but equally strong headers. A high ratio of heat transfer surface to volume of contact mass is used, this being important in effecting adequate temperature control throughout the entire contact mass. When such extra surface is used, this extra surface is utilized also to define the flow paths through the contact mass.

The foregoing novel features are important in practical operation. The optimum and limiting values of the ratios, etc., mentioned above are important to the invention and have now been reasonably well determined and are set forth in detail below. The above-described requirements for best operation have been verified by actual trial and experimentation. Adherence to the novel principles and limits set forth herein .results in advantages of extreme importance lower yield per unitvolume' of contact mass-and] per unit volumeofmaterial charged. If it is attempted to force the operationto offset some of these disadvanta-ges, other serious objections are encountered including destruction of the catalystbecauseof excessively intense burning at localized points.

'To completelyund-erstand the process to be practiced, reference is now made to the drawings attached to this, specification; "In these drawings, Figure 1 showsa longitudinal sectional.

view of one form of theapparatus; Figure '2 shows a cross-section of that form, and Figures 3, 4, 5 and ,6, set forth-certain optional arrangements which-maybe used.'tl'lerein. Figures .7 and 8 show longitudinal sections in planes 90 apart of another'form of apparatus embodying the same general characteristics. Figure 9 is a diagram explaining one feature of the invention. Figure 10 is a sketch showing a-longitudinal section of a form of apparatus embodying the same essentials and of greater utility for commercial practice of the invention. Figure 11 is a crosssection of the apparatus: shown in Figure 10.- Figures l2 and 13 show an alternative general form of apparatus. Figure 14- is an illustration of how the apparatus may be set and operated for commercial practice of the process to be conducted therein.

Referring now to Figures 1 to 6, inclusive, Figure 1 shows a longitudinal section in somewhat diagrammatic form of an'apparatus embodying the essential featuresvn-ecessary for the practice of our invention. The apparatus of Figure 1v plate 22, similarly, is placed between members I3:

and I5, and tubes 20 similarly pass through orifice plate 22. Theend member I! is equipped with an inlet fitting 23 and end member It is equipped with an outlet fitting 24. Inlet member 25 communicates "with the space inside of member I5 between plates I9 and 22, surrounding tubes 20. Outlet member 26 communicates with the space within member It between plates [8 and 2|, and around tubes 2H. Orifice plates '2! and 22 are equipped with orifices 21, distributed uniformly over that/portion of their area not occupied by passages for tubes '20. Oil entering through inlet '25 will pass through the orifices 2'! in plate 22., longitudinally through the space within the shell 13, through the orifices Z! in plate 2i, and leave. the system through fitting 26. A heat exchange fluid may enter through 23, pass through tubes 20 and leave the apparatus through fitting -2 4 without coming in Orifice plate 2| is placed between 7 physical contact withthe oil; Tubes 2U-being constructed of heat conductive material, the two fluids are in heat exchange relationship. The direction of flow of either fluid may be changed without altering this relationship. The shell I3 serves as the container for a catalytic or contact mass preferably composed of granular par-v ticles. This contact mass may be introduced and removed by making use of the openings normally covered by plates 28 and 29.

The design and arrangement of the tubes 20 within the shell I3 is suchthat these tubes 20 also serve todivide the catalyst bed-maintained in shell I3 into a large number of longitudinal passages, Whose greatest length is parallel to the and at the same time to furnish a maximum re-.,

sistance to lateral flow, although it is preferred that no unit path or passage be completely-isolatedfrom contact with other pasages for reasons stated above. ,Thearran-gement is preferably such as to give a substantially uniform cross-sectional area of catalyst throughout the length of each passage and of the catalyst case,

which of itself promotes longitudinal fiow under uniform conditions.

Figure 2 shows a cross-section of the catalystcontaining portion of the apparatus of Figure l and sets forth a convenient and economical arrangement of tubes and fins to accomplish these purposes, which arrangement is shown in more detail in Figure 3. Figures 4:, 5 and 6 show other optional arrangements of finned tubes. In these figures the setup is designed for the circulation of heat exchange medium inside the tubes, the. contact mass being outside.

It-is also possible to preserve the longitudinal positioning of the passages within the catalyst masswhile making use of heat exchange tubes positioned transversely thereto. In Figures 7 and 8 two views are shown of a design in which this is accomplished. This apparatus consists of a catalyst casing 3|, mounted above a reaction mixture inlet housing 32, which is divided:

change medium which may enter b 4b, and. leave by M, orthe reverse, and which is con-.

ducted through the catalyst bed by a series of tubes 42 extending from side to side of the cata-. lyst case These tubes arearranged in vertical rows and are preferably equipped with fins 43,

the tubes and fins being arranged so as to sub-- divide the catalyst mass into a number of longitudinally extending paths of relatively great length in proportion to cross-section, as shown.

This object may also be approximated by using.

smaller vertical spacing of .unfinned tubes, hile maintaining the same horizontal spacing.

As stated above, certain factors or proportions-- in the design of the-apparatus are important. 1

Taking a typical-example, where the catalyst mass is composed of granular particles of clay, which may themselves be the catalyst or in and/or on which an active catalytic material such as a metallic oxide is deposited, the following criteria may be used as typical of commercial design. The dimensions of the apparatus and tube spacing should be such that the unit reaction paths defined thereby should be 3 or more feet in length, or up to feet or more, and having at least one cross-dimension relatively short, preferably not exceeding 1 to 2 inches. The several ratios stated elsewhere herein should be observed. The maximum distance of any catalyst particle from an heat extraction surface preferably should be about /2 inch, and not more than about 1 inch. The average distance of any catalyst particle from a heat extraction surface is preferably about 4 inch, and not more than about inch. When fins are used, to insure proper heat transmission, design should be such that A T(fin), the temperature drop from fin tip to fin base should not be greater than about and preferably about 10% of A T(total), the temperature drop from catalyst bed to heat exchange medium. Designed proportions of fins should be such that for any cross-section of the fin, Z, the length of the cross-section, divided by d, the least transverse dimension of fin, (see Figure 3), should not be greater than about 12 and preferably about 4 to 8. That is,

- =preferably 4 to 8 The optimum dimensions, ratios, etc. given herein are based particularly upon use of a cylindrical catalyst granule about 2 min. in diameter by about 4 mm. average length, or any other shape having a like mass and percentage of void per unit volume of packed catalyst. As the catalyst particle size increases, the ratio of heat extraction surface to unit catalyst volume may decrease and the maximum distance of catalyst particle from heat extraction surface may increase. The same changes may be made with a catalyst mass of greater heat conductivit than that indicated. When the design controlling operation is that of regeneration, a high degree of coking will call for increased heat extraction surface relative to catalyst volume ratio and decreased maximum distance, and conversely. It will be understood, therefore, that the optimum specific dimensions, ratios, etc. will vary somewhat according to the particular needs of a par ticular operation. No claim is made herein to any particular composition or physical form of catalyst or contact mass.

An important feature in apparatus shown by these figures is the restricted intercommunication of one series of conduits intermediate their ends. For any given zone layer along the flow paths through the contact mass, which zone may be considered as being relatively thin and at substantially uniform static pressure under normal conditions of flow, the free area for flow between conduits in a transverse direction is relatively small compared with the free area in a direction longitudinal to the flow of reaction material. Normal flow is largely longitudinal of the respective conduits but substantial flow between conduits to compensate for abnormal conditions is possible. Furthermore, the embodimerit of these features in combination with preferred relationships defined herein constitutes an important feature of this invention.

To understand how uniform distribution of flow may be accomplished, reference is made to Figure 9 of the drawings, in which there is shown in diagrammatic form three passages, 44, 45 and 45, each packed with contact mass and between which there is restricted communication at intervals along their length by cross passages 41. In passage 44 there is a stoppage 48, indicated by denser packing of the contact mass. Equal amounts of reaction mixture, as indicated by the flow lines, are introduced at the bottom of the several paths. Only a portion of that normally flowing in path 44 can pass through the stoppage 48. As indicated by the flow lines, the remainder will pass through some horizontal intercommunication 41 below the stoppage, be distributed among the other paths and again through some other horizontal passage 41 above the stoppage it will return to passage 44, so that in this mannor there is maintained throughout the case a substantially uniform distribution of flowing reaction material among the several paths and along their length by virtue of their restricted lateral intercommunication.

Figure 10 of the drawings shows a form of reaction case which not only admirably embodies the essential features of our invention, but which is perhaps more adaptable for the commercial practice of the invention than theform shown in Figure 1, in that it is able to successfully withstand the strains and distortions set up by differential expansion of the several parts of the apparatusupon heating and cooling. The apparatus shown in longitudinal section in Figure 10 is enabled to handle these stresses by means of an internal floating head arrangement. The apparatus of Figure 10 consists of a. shell 49, to which are attached end sections 50 and 5|. Reaction mixture is admitted to the shell space 49 by inlet fitting 52 and reaction products are withdrawn by outlet fitting 53 in end member 5|. Between shell 49 and end member 50, there is placed a heavy tube sheet 54 in which are rolled tubes 55. These tubes 55 at their upper end are secured in the tube sheet member of floating head 55. A large central tube 51 is also secured between tube sheet 54 and the floating head 56. Heat exchange medium is introduced by inlet fitting 51', led to the space within end fitting 50, through tubes 55 into floating head 56, thence into central tube 51 and out through outlet 58. The tubes 55 are equipped with fins 59 as before.

Catalyst is confined between support plate 60 w and plate 6|, both of which have orifices 62 for the passage of reaction mixture therethrough.

To support plate 60 some distance above tube sheet 54 and thus provide a plenum chamber for the introduction of reaction material, there are used short lengths of pipe 63 surrounding tubes 55, resting on tube sheet 54 and supporting orifice The fins 59 on tubes 55 extend between plates 60 and 6|, and plate 6| conveniently may be supported upon the upper ends of these fins if it be so desired. This apparatus is arranged to be installed in vertical position and may be supported conveniently by the skirt 54 at the infrequentintervals necessary, by lifting shell 49 free from tube plate 54 until the catalyst may be removed from above plate 60. It is obvious that in this design the direction ofpassage of either reaction material or heat exchange medium may be reversed from that indicated while preserving the essential features of operation shown. It will be seen that in this design convenient provision for the handling of differential heat expansion and the like has been made and a design convenient and economical of fabrication has been attained. Figure 11 shows a horizontal cross-section of Figure 10, taken at a point between the ends of the catalyst-containing space.

It may be seen that these various forms of apparatus all embody one general characteristic. They permit the use of catalyst masses which are relatively of great length in the direction of reaction material flow and which have at least one dimension transverse thereto of relatively small magnitude, so that each portion of th catalyst therein is in effective heat exchange relationship with a positively circulated heat exchange mediumby which its temperature may be controlled while in operation. Each design accomplishes this by arranging in one form or another, aseries of conduits extending longitudinally of the direction of reaction material flow, which conduitsare filled with a catalytic, mass, and then surrounding and/or defining these with other conduits through which flows 2. heat exchange medium. Each design observes certain rules of, proportion of parts whichare set forth herein, and upon which the unique capabilityof the operation is in large part based. Provided that these rules of proportion of parts are followed, the method of operation set forth herein also may be followed in forms of construction wherein the catalyst mass is contained in tubular members properly spaced. one from another, and surrounded by positively circulatedheat transfer medium. Such construction is shown in Figure I 12 and Figure 13.

In Figure 14, showing an operating setup for commercial practice of this invention, II is a heater for charge, 12 a vapor separator, 13 and M are catalyst cases, 15 is a vfractionator for treatment of processed vapors, 16 a condenser, and. T! a gas separator. Charge stock enters the system through pump 18, and, by means of the manifold arrangement shown, any portion of it may be passed through heat exchangers l9 and 80 in any sequence desired, to be later'collected in pipe 81 and passed through furnace heater H and into vapor separator 12, where a vaporous charge for the catalytic process, substantially free from liquid and materials of unduly high boiling point is prepared. In case the charge stock selected is wholly ,vaporous at the desired reaction temperatures, the vapor separator may be dispensed with. Any liquid separated in 12 may be removed from the system by pipe 82. Vapors from 12 pass through pipe'83, and if catalyst case 13 be on streamthrough pipe 84 into case 73, the valve in pipe 85 being closed. Passing through catalyst case 13, the treated reaction mixture leaves through pipe 86, pipe 81 being closed, and through pipe 88 to fractionator 15. Material heavier than desired product is condensed in Hand withdrawn through pipe 89- to storage, or it may be recycled in company with charge, or it may be retreated in another step of catalytic or thermal conversion. Product vapors leaving 15 through pipe 90 are condensed in i6, and separated from uncondensible gas in 11. While catalyst case 13 is on stream catalyst case 14 will be regenerating. Regeneration medium (in this operation air is used), is supplied by compressor 9|, and passed through pipe 92 into case 14. 'Regeneratlon gases, leaving case M bypipepfit', may pass either through cooler 94 or through cooler '89 and after.recovery of heat therefrom, are discharged to the atmosphere. Cooler 94 may be water cooled, or may be a'waste heat boiler, or may heat charge for other processes, and any suitable division of flow through these two cooling means may be used. Heat transfer medium is supplied under pressure by pump $5 to discharge manifold 96, from which any desired disposal may be made to the tubes in casesl3 and 14, the heated medium, recollected in manifold 9'! being passed through cooler 19 before return .to the pump.

In the usual case, in the setup shown, the heat transfer medium is cooled to a temperature somewhat above the reaction. temperature in case 1'3,

and a sufficient volume is passed through case 13 to supply endothermic reaction'heat and at the same'time insure even distribution of reac-, tion therein. Another portion is passed through case 14, sufiocient'in amount to controldistribution of the regeneration reaction therein, to remove excess reaction heat therefrom, and to supply kindling heat to theincoming regeneration air. The heat transfer medium may be any suitable fluid, but is preferably a liquid such as amolten metal, a molten alloy, or fused inorganic salts, or other liquid possessed of low vapor pressure, of high heat absorbing capacity per unit volume per degree temperature change, and reasonably low viscosity at the temperature, (200 F. to 1100 F.) at which it is used.- Preference is'given to materials oflow vapor pressure melting below 350 F., so that the medium may be removed from shutdown apparatus by steam heating. Convenient materials are mixtures of aluminum chloride and sodium chloride; of zinc,

case I l is put on stream and case 13 isregenerated.

stated .above, various relationships and ratios'involving. such....r natters as amount of heat transferring surface, volume of heat exchange medium and volume'of contact mass are important features of the invention, andhavebeen reasonably well determined by actual operation I and experimentation. The followingflgures represent a preferred relationship which hasbeen' found to operate satisfactorily. It will be understoodthat the'figures' given'refer only to that portion ofthe apparatus which contains the contact mass and do not include'the adjacent zones where tube headers, heat exchange medium manifolds or distribution spaces, and vapor passages exist but which do not contain contact mass;

This is also true of the figuresstated in the claims.

Volume of catalyst including voids Volume of heat exchange metal (tubes and fins)- 19. 6 Volume occupied by molten salt in tubes 9.

Total (volume of space occupied by catalyst, salt, and heat exchange surfaces) 100 Heat exchange surface per cubic inch of molten salt 19. 7 square inches Heat exchange surface per cubic inch of metal in heat transfer tubes and fins Heat exchange surface per cubic inch of molten salt plus metal G. 2 square inches Heat exchange surface per cubic inch of catalyst" 2. 5 square inches 9. 0 square inches We give the following data to define the preferred range for best design and operation:

Volume of catalyst including voids 60-80% of space in catalyst zone Volume of molten salt 2l5% of space in catalyst zone Volume of metal (tubes and fins) 15-30% of space in catalyst zone Volume of catalyst plus salt plus metal 100.00% of space in catalyst zone Heat exchange surface per cubic inch of molten I alt 15-60 square inches 5 Heat exchange surface per cubic inch of metal in heat transfer tubes and fins.-. Heat exchange surface per cubic salt plus metal 4-12 square inches Heat exchange surface per cubic inch of catalyst. 1.5-6 square inches give below figures defining relationships beyond the limits of which operating difficulties would arise which would seriously impair the efliciency of the process or would increase the cost to a most undesirable level as compared with our preferred design and operation.

Volume of catalyst including voids. 40 .90% of space in catalyst zone Volume of molten salt l25% of space in catalyst zone Volume of metal (tubes and fins) 550% of space in catalyst zone Heat exchange surface per cubic inch of molten salt 5-100 square inches Heat exchange surface per cubic inch of metal in heat transfer tubes and fins 3-30 square inches Heat exchange surface per cubic inch of molten salt plus metal 2-20 square inches Heat exchange surface per cubic inch of catalyst. 0.5-8 square inches These relationships and ratios, as herein set forth, define the relationship between the hydraulic radius of the catalyst path, the mass velocity of the critical reactant and the mass velocity of the heat exchange medium. The term (hydraulic radius as used here is the factor defined in Perry-Chemical Engineers Hand Book (McGraw Hill Book Company) (1934) at page 722. The design is controlled by the ratio of heat transferred to heat liberated or absorbed in the catalyst. The heat liberated during regeneration is substantially the greatest quantity; Under proper conditions, as herein set forth, this heat liberation may be made substantially uniform per unit volume of catalyst. Similarly, heat transfer may be made uniform per unit area of heat transfer surface. The proper proportion of catalyst volume to surface defining that volume is then shown by Heat liberated per unit time per unit volume HR Heat transferred per unit time per unit area wherein HR is a quantity of the nature of a hydraulic radius, having the dimension of length, and as shown herebefore ha a, broad range of from /8 to 2" and a preferred range of from completeness of regeneration.

/6" to The rate of heat liberation per unit volume of catalyst is a function of the mass velocity of 'air (regeneration medium) in weight per unit volume of catalyst per unit of time, in proportion to coke to be burned from said catalyst, which may be applied without excessive rise in temperature suflicient to damage the catalyst. This may be expressedas a burning rate, which, while not exceeding about l,000 F. under condi tions of operation, will remove coke at-the rate of from about 1% by weight of catalyst to about 10% per hour for a broad range of possible operation, and from about 3% to about 6% for preferred operation. The mass velocity of heat transfer medium of course depends upon the specific heat and other characteristics of the medium. It is best defined as thatmass velocity of heat exchange medium which will extract the required amount of heat while undergoing a tem- 20 ,perature rise of not greater than about 50 F. and

preferably of from 2 to 10 F.

Some of the advantages of the method of this invention are high throughput rates per unit volume of catalyst, high conversion rates at acceptable throughputs, low coke from side and subsequent reactions, low gas from like reactions, uniformity of reaction throughout the catalyst bed, uniformity of kind of product produced from all portions of the bed, uniformity of deposit of coke and reaction products throughout the bed, and other advantages, all of which also result result indirectly in higher unit yields. As an important contribution to the flexibility and ase of control of the process, temperature of the entire body of heat transfer medium is capable of such rapid adjustment, that difficulties due to variation in temperature level of incoming reaction mixture are practically wiped out. This is of especial time saving importance in changing over from one reaction to another, as for example, taking a case 01f stream in a polymerization operation at about 300 F. and putting it into regeneration at about 850 F. Separate exchangers for heating or cooling may be installed between pump and the respective cases 13 and 14 if desired.

The regeneration step also benefits greatly by the invention herein disclosed. The regeneration reaction is substantially uniform throughout the mass, both because the distribution of regeneration gases is uniform, and because the reaction having been substantially uniform, the density of reaction deposits is also substantially uniform. The regeneration is far more rapid with equal delicacy of temperature control and The control of regeneration temperatures is easy, accurate, and positive, thus further promoting uniformity. Regeneration can be effected with atmospheric temperature air, eliminating expensive preheater installations formerly thought to be necessary. The regeneration heat is rejected from the system at higher temperature levels. The heat transfer medium offers: an effective means whereby some of this regeneration heat may be supplied to, the cracking reaction for latent heat uses.

An important feature is the ability to purge in this process, between case changes, by the simple use of steam. Some catalytic methods, because of their inherent tendency to by-pass and channel, cannot be steam purged effectively without extremely long and uneconomical steaming, It has been found that when using the reaction method herein disclosed, the catalyst cases maybe purged easily and completely by the simple application of steam under some pressure.

With the high charging rates possible with this invention greatly increased yields per unit of time, per unit of catalyst volume and per dollar of apparatus cost are possible. High percentage of yield on the charge can be obtained by re- The catalytic reaction is preferably conducted under a gauge pressure not substantially in excess of 30 to 40 pounds per square inch. Rates of coke deposition per unit yield increase rapidly with increases in pressure, and the preferred operation is at pressures: ranging from atmospheric upwards to about pounds per square inch gauge. Underthese conditions, it is necessary to recompress fixed gases yielded by the process in order to introduce them to the customary vapor recovery operations, but this cost is more than regained by lower cost of regeneration. With stocks tending to form very little coke, pressure may be raised to the range to pounds gauge and recompression of gases avoided without sacrifice of good regeneration conditions.

The catalytic reaction for conversion of other oils to gasoline may be conducted at temperatures. in the catalyst mass between about 810 F. n

and about 950 F. and preferably between 875 F. and 900 F. The rate of charge for such conversion will usually be in excess of twenty liters of liquid charge per hour pertwenty, liters of catalyst mass, and should preferably be at least fifty liters liquid: charge per hour per twenty liters of catalyst. Such rates of charge and temperatures, using a charge which is clean, i. e., substantially' free of unvaporized particles of high boiling oils and the like, prone to heavy coke formation, should result in a coke deposit amounting to from about 0.1% to about 2.0% by Weight of the catalyst, (average condition throughout the case), and under the preferable ranges of operation, from 0.2% to .1.5% by weight of catalyst.

.The regeneration operationshould be conducted by the introduction of air at atmospheric temperature and under pressures very slightly above atmospheric, sufficient only to insure flow through the apparatus at the requisite rates. The temperature of regeneration should range from about 825 F. to about 1,000 F. Preferred operation is at about 900 F. and with a clay type catalyst, 1,000 F. should not be exceeded due to possibility of rapid catalyst deterioration above those temperatures. The rate of air intro-- duction should be such that the proper temperatures are maintained While burning off coke at vention 'isnot limited thereby except as such limitations. are, expressed in the claims.

What is claimed is: i 1. A process for efiecting the conversionof hydrocarbons into hydrocarbons of the gasoline type, comprising passing the hydrocarbons to be converted, in a vaporized state, in a plurality of paths through a body of contact material, while maintaining all portions of the contact material and contacting vapor at substantially uniform temperature within a range where substantial conversion of the hydrocarbons will take place with resultant deposition of a contaminating combustible substance upon the contact material, continuing such passage of hydrocarbons and the conversion thereof until the deposit upon the contact material renders it inefficient and regeneration is desirable, removing vapor products from contact with the contact material, passing combustion supporting gas through the used con.- tact material to effect regeneration thereof in situ by flowing said gas through the body of contact material in the form of streams, the effective heat exchange peripheries of which are greater than the minimum periphery required to encircle their cross-sectional area, said streams each being sumciently thin in at least one dimension to main tain the temperature difference between portions of said contact material across transverse sec tions thereof within a range not exceeding the difference between the minimum temperature at which the burning of contaminating combustible material occurs and a maximum temperature above which substantial damage to the contact material occurs and being of a length several times its narrowest cross-sectional dimension, each of said streams being in restricted communication throughout substantially the entire length thereof with at least one stream adjacent thereto, and continuously removing heat from the burning areas by the use of a heat control medium circulatedthrough the contact materialin conduits, and in sufficiently intimate relation to the contact material to maintain all portions of the contact material within the operative temperature range.

2. A process for effecting the conversion: of hydrocarbons into hydrocarbons of the gasoline type which comprisespassing the original hydrocarbons in a vaporized state ina plurality of paths through a body of contact material whil'e'maintaining all portions of the contact material and contacting vapor at a substantially uniform temperature within a range Where substantial conversion of the hydrocarbonswilltake place, continuing such passage of hydrocarbons and the conversion thereof until the contact materialbecomes inefficient and regeneration is desirable, removing vapor products from contact with the contact material, passing combustion supporting. gas through the body of used contact material to effect regeneration thereof in situ by flowingsaid gas through the contact material in the form of streams defined to a substantial extent by heat exchange surfaces, said streams each.

being sufficiently thin in at least one dimension to maintain the temperature difference between portions of contact material across transverse material occurs and a maximum temperature above which substantial damage to the contactmaterial occurs and being of a length several times its narrowest cross-sectional dimension, each of said streamsbeing in restricted communication throughout substantially the entire lengththereof with at least one stream adjacent thereto, and continuously removing heat from the burning areas by the use of a heat control medium in sumciently intimate indirect heat exchange relationship to the contact material through said heat exchange surfaces to maintain all portions of the contact material within the operative temperature range.

3. A process for effecting the conversion of hydrocarbons into hydrocarbons of the gasoline type which comprises passing the original hydrocarbons in vapor phase in a plurality of paths through a body of contact material while maintaining all portions of the contact material and contacting vapor at a substantially uniform tem perature within a range where substantial conversion of the hydrocarbons will take place, continuing such passage of hydrocarbons and the conversion thereof until the contact material becomes inefficient and regeneration is desirable, removing vapor products from contact with the contact material, passing combustion supporting gas through the used contact material to effect regeneration thereof in situ by flowing said gas through the body of contact material in the form of streams defined to a substantial extent by heat exchange surfaces, said streams each being sufficiently thin in at least one dimension to maintain the temperature difference between portions of contact material across transverse sections thereof Within a range not exceeding the difference between a minimum temperature at which the burning of the contaminating combustible material occurs and a maximum temperature above which substantial damage to the contact material occurs and being of a length several times its narrowest cross-sectional dimension, each of said streams being in restricted communication throughout substantially the entire length thereof with at l ast one stream adjacent thereto, and continuously removing heat from the burning areas by the use of a heat control medium in sufficiently intimate indirect heat exchange relationship to the contact material through said heat exchange surfaces to maintain all portions of the contact material within the operative temperature range, the heat control medium being maintained at a temperature substantially approaching the lower limit of the temperature range within which regeneration will occur.

4. In a process for making gasoline involving converting hydrocarbons into other desired hydrocarbons within the gasoline range by contacting the original hydrocarbons in vapor phase with a body of contact material that effects such conversion, accompanied by the deposition of a nonvolatile combustible substance upon said contact material, and then burning the combustible deposit oil? of said contact material, the steps of passing the hydrocarbons through the body of contact material in a plurality of elongated paths of at least about three feet, to effect the desired amount of conversion, continuing such flow of hydrocarbons until the deposit upon the contact material is such as to render regeneration thereof desirable, and thereafter regenerating the contaminated contact material in situ in said elongated paths by passing the combustion supporting gas into the used contact material throughout all portions thereof to effect burning of said deposit throughout all parts of the contact material, flowing said gas through said body of contact material as aforesaid in the form of thin streams defined to a substantial extent by heat exchange surfaces sufficiently thin in at least one dimension to maintain the temperature difierence between portions of the contact material across transverse sections of said respective thin streams within a range not exceeding the difference between the minimum temperature at which effective burning of said deposited combustible substance occurs and the maximum temperature above which substantial damage to the contact material occurs, each of said streams being in restricted communication throughout substantially the entire length thereof with at least one stream adjacent thereto, continuously removing heat from burning areas within the contact material by abstracting said heat throughout a substantial proportion of the respective outer surfaces of said thin streams transversing said areas through said heat exchange surfaces to a heat control medium, withdrawing said heat at a temperature level sufficiently high to permit continuance of the desired burning but sumciently low so that the maximum temperature of the aforesaid limited temperature range throughout the entire length of each of said elongated thin streams will not exceed the temperature above which substantial damage to the contact material occurs, and continuing burning as aforesaid until the contact material has been adequately freed of the combustible deposit.

5. In a process for making gasoline involving converting hydrocarbons into other lower boiling point hydrocarbons by contacting the original hydrocarbons in a vaporized state with a, body of contact material that effects such conversion, accompanied by the deposition of a non-volatile combustible substance upon said contact material, and then burning the combustible deposit off of said contact material, the steps of passing the hydrocarbons through the body of contact material in a plurality of elongated paths to effeet the desired amount of conversion, continuing such flow of hydrocarbons until the deposit upon the contact material is such as to render regeneration thereof desirable, and thereafter regenerating the contaminated contact material in situ in said elongated paths by passing combustion supporting gas into the used contact material throughout all portions thereof to effect burning of said deposit throughout all parts of the contact material, flowing said gas through said body of contact material as aforesaid in the form of streams defined to a substantial extent by heat exchange surfaces, each of said streams being sufiiciently thin in at least one dimension to maintain the temperature difference between portions of the contact material across transverse sections of said respectivelthi'n streams within a range not exceeding the minimum temperature at which effective burning of said deposited combustible substance occurs and the maximum temperature above which damage to the contact material occurs and of a length several times its narrowest cross-sectional dimensionQeach of said streams being in restricted communication throughout substantially the entire lengththereof with at least one stream adjacent thereto, continuously removing heat from burning areas within the contact material by abstracting said heat throughout a substantial proportion of the respective outer surfaces .of said thin streams transversing said areas through said heat exchange surfaces, withdrawing said heat at a temperature level sufficiently high to permit continuance of the desired burning but sufficiently low so that the maximum temperature of the aforesaid limited temperature range throughout rial occurs, and continuing burning as aforesaid until the contact materialhas been adequately freed of the combustible deposit. a

6. In a process for makin gasoline involving converting hydrocarbons into other desired. hydrocarbons within the gasoline range by contacting the original hydrocarbons in vapor phase with a body of contact material that effects such conversion, accompanied by the deposition of a nonvolatile combustible substance upon'said' contact material, and then burning the combustible deposit off of said contact material, the step of re generating the contaminated contact material in situ by passing combustionsup-porting ga into the used contact. material throughout allportions thereof to effect burning of said depositthrougm outall parts of the contactmaterial, flowing said 'gas through said body of contact material as aforesaid in the'form of streams defined to a substantial extent by. heat exchange surfaces, each of said streams being sufiiciently thin in atleast one dimension to maintain the temperature differences between portions of the contact material across transverse sections of said respective thin streams within a range not exceeding the minimumtemperature at which effective burning'of said deposited combustible substance occurs and the maximum temperature above which substantial damage to the contact material occurs and being of a length several times: its narrowest cross-sectional dimension, each of said: streams being in restricted communication throughout substantially, the entire length thereof with at least one stream adjacent thereto, continuously removing heat'from burning areas; within-the contact material .byv abstracting said heat in a direction substantially parallel to the minimum transverse dimension of the respective thin streams and throughouta substantial proportion of the respective outer surfaces. of said thin streams as they transverse said area through said heat exchange surfaces, :withdrawingrsaid heat at a temperature level sufficiently high to permit continuance of the desiredburningbut sufficiently low so that the maximum temperature of the aforesaid limited temperature range throughout the entire length of -eachof; saidthin streams will not exceed the temperature above which substantial damage to the contact material occurs, and continuing burning-gasaforesaid until the entire contact material has; been ade; quately freed of the combustible deposit I v 7. In a process for making gasoline involving converting hydrocarbons into other desired hydrocarbons within the .gasolinerange by contacting the original hydrocarbon in vapor phase with a bodyof contact material that effects such conversion, accompanied by the deposition of .a nonvolatile combustible substance upon said contact material, and then burning the combustible deposit'offfof said contact material in situ, the

stantial extentby heat exchange surfaces, each ofx'saidlstreams. being sufiiciently thin in at least one dimension to maintain the temperature 1. dif

ference between portions of the contact material 'acros's tr-ansverse ectionsof said respective thin streams within a range not exceeding the minimum" temperature at which effective burning of said deposited combustible substance occurs and the maximum temperature abovewhich substantial damage to. the contact material occurs, each of "said streams being inrestricted communication throughoutsubstantially the entire length thereoi with at least one stream adjacent thereto, continuously removing heat from I burning areas within the contact material by the use of a heat control medium maintainedlat a'temp'erature substantially approaching the lower limit of the temperature range within which burning occurs, abstractingsaid heat throughout a substan tial proportion of the respective outer surfaces of said thin stre'amsutransversingl said areas through said heat exchange surfaces, and continuin burning. as aforesaid until. the contact materiallhas .been adequately freed of; the combustible deposit, thereafter passing hydrocarbon vapors intois'aid body of contact material accompanied; by, the deposition ofca non-volatile combustible substanceuponsaid contact material, and then, burning the combustible depositv off or :saidcontact material in situ,;thezsteps of pass.-

ing combustion-supporting,gasinto the used contact materialthroughout all portionsthereof ,to

Effect burning Y ofsaid: :depo'sit; throughout all parts of the contactjmaterial, flowing saidgas through said-body of contact material as aforesaid in a plurality. ofelongated paths of a length of at least about'three feet in the'form of streams definedto, asubstantial extent by heatexcjhange surfaces, each of said streams being-sufficiently thin in at least, one dimension :to; m'aintainthe temperature 1 difference between portions of the contact material across transverse sections .of said respectivethin streams within, a range. not exceeding, the minimum; temperature; at which effective burning" of said. deposited combustible substance occurs and the maximumtempera'ture above which substantial damage to the contact material occurs, and being of Ia'length several times the, narrowest cross-sectionaldimension, each of said streamsbeingin restricted communication throughout substantially thejentire length thereof with at least one stream adja'cent there to, continuously removing heat from; burning areas withinthe contacttmaterial .byI abstracting said heat throughout a substantial pr'oportionv'of the respective outer'surfaces of said'th'instreams transversing, said areas throughsaid lieat exchange su'rfaces-to a heat control medium main tained jin indirect heat. exchange relationship .with. said contact material, withdrawing said heat at aztemperature level sufficiently high to permit continuance A of the desired burning -b'ut' sumcientlylow so that'the maximum temperature of the aforesaid limited temperature range throughdimension to maintain the temperature difference between portions of .the contact material within a range not exceeding that which is permissible inefiecting the desired conversion.

9. A .process .for "effecting the conversion of hydrocarbons =.into hydrocarbons of'the gasoline type, comprisingipassingpthe I hydrocarbons .to be converted, in phase,-in.aplurality of-lpaths through aubody :of contact material awhile-maintaining :illportions 0f the: contact material and contacting vapor within a temperature range Where substantial conversion of the hydrocarbons will take place .wi-th'resulta'nt deposition of a contaminating combustible substance upon the contact material, continuing such passage'of hydrocarbons-and th'econve-r-sion thereof until the deposit upon the contact material renders it inefiicient-and regeneration is desirable, removing vapor 'products' trom contact with the contact material, passing combustion supporting gas through the used contactmaterialto e ffe'ctregeneration thereof in situ "by flowing said gas through the body of-contact materiabin'th-e Ionn of thin streams suiiicientl'y thin inoat least one dimension to maintain the temperature difference between portions-oi said conta'ct material across transverse sections of respective thin streams within a range not exceedingthe d iiference between :a 1 minimum temperature at which the burning orthe contaminating depositoccurs and :a maximum temperature above which substantial damage to the contactmaterial occurs-and being of: a length several-times theinharrowe'stcmsssectional dimension, each of saidstreams being in restrictedscommunication throughout'substantially theentirelength thereof with -at least one stream adjacent thereto, and continuously removing. heat from the burning-areas l within 'the contact material to maintain the temperature thereof below that at which substanti al damage occurs, by maintaininga heat control me'diwn in indirect heat exchange relationship with said contact material. I v I I 10. A process for effecting the conversion of hydrocarbons into hydrocarbons of I. the gasoline type, comprising. passing a the hydrocarbon to be converted, in-vapor phase, in a plurality of paths through contact material, while maintainin'g all portions of the contactwmaterial and co'ntacting vapor within a' temperature range where substantial conversion of the hydrocarboniwilLtake place with resultant deposition of :a contaminating combustible substance upon. the; contact material, continuing such passage of hydrocarbons and the conversion thereof until the deposit upon the contact material renders it ineflicient and regeneration is desirable, removing vapor products from contact with the contact material, I passing combustion supporting gas through the used con tact material to effect. regeneration :thereof in situ by flowing said gas. throughthe contactmaterial in the form of thin streams defined at least to a major extent by heat lexchange surfaces, said streams being sufliciently thin in at least one dimension to maintain the temperature difierence between portions of said contact material across transverse sections of respective'thin streams within a range-not exceeding the diiference between a minimum temperature at which the burning of; thecontaminating deposit occurs and a maximum temperature above which substantial damage to the. contact materialoccurs, each of said stream-s being "in restricted communication throughout substantially the entire length thereof with at least one stream adjacentthereto, and continuously removing heat (from the burning areas Wlthintlre cont-actmater-ialto maintain the temperature thereof belowu that at which substantial damage-occurs, by :fiowing a heat control medium in heat transfer relationship with said heatexchange-surfaces, whereby it is in indirect heat exchange relationship with said contact material said heat control-medium being maintained in the liquid phase at aetemperature substantially between the minimum temperatureofv conversion I and the rmaxim-um temperature of regeneration.

"11. A process for effecting the "conversion of initial fluid hydrocarbons into fluidihydrocarbon .Droducts, comprising passing the xhydrocarbon to lie-converted, in :a fluid statepin a plurality of paths through contact material, while maintaining all portions oi the contactmateri'al'and contacting :iiuid within .a temperature .lrange where substantialconversion I of the hydrocarbon will take place with resultant deposition-of a contaminating combustible substance upon-the contact material, continuing-such passage-0f hydrocarbons and the conversion H thereof until the deposit upon thereon-tact material renders it ineificient o and regeneration is desirable, removing fiuidi'hydrocarbonsgiromcontact with the contact material, passing combustion supporting g-as throughthe used contact .materia l to effect retgerierationthereof in -situ by flowing said gas through the contact mate-rial in the form of thin streamsdefined cat least, to a major extent by heat exchange s'urtacea'said streams beingsuificiently thin in at least one dimension to m-ain tain t'he temperaturedifference-between portions of-said'contact material "across transverse sections o-f respective thin streams within a range not exceeding the "difierencc be'tween aminimum temperature at which the burning ofthe con taminating deposit occurs-and amaximum temperature above-which substantial damage to the contact -materi-al-occurs, each of saidstreams being 'in" restricted communication throughout substantially the entire length thereof withwat leastone stream adjacent thereto, and continuously removing heat from-the 'burning areas within. the contact material to maintain the temperature thereof :below that at whlch substantial damage. occurs, V by Snowing a :heat control medium in' 'heat transfer relationship with heat exchange surfaces, whereby it isaini indirect heat cexchange relationship with .zsaid contact material, said. heat control medium :belng; main.- tained in the liquid phase at. a temperature substantially between the minimum temperature :of conversion'and. the. maximum :'temperature:-:of

regeneration. 1..

1 12. 1 In :aaproc'ess; of convertingliinitialrfluid hydrocarbons rinto rlluidihydrocarbon rdducts;by

.passingcsaid initial: fluid hydrocarbons through contact material; of catalyst paths, continuing h p ssage ot-"hydrocarbons until drocarbons into fluid hydrocarbon products by passing said initial fluid hydrocarbons through contact material in a plurality of catalyst paths,

continuing such passage of hydrocarbons until deposition of a combustible contaminating deposit on said material renders the same inefiicient,

and regenerating the contaminated contact material by passing a combustion supporting gas therethrough; the improvement which comprises passing said gas through said contact material in the form of a plurality of streams defined at least to a major extent by heat exchange surfaces and abstracting heat from said contact material through said heat exchange surfaces, each of said streams being in restricted intercommudeposition of a combustible contaminating de- 1 posit on said material renders the same ineflicient, and regenerating the contaminated contact material by passing a combustion supporting gas therethrough; the improvement which comprises passing said gas through said contact material in the form of a plurality of streams defined to a major extent by heat exchange surfaces, each of said streams being in restricted intercommunication with at least one other of said streams adjacent thereto throughout substantially the full extent of a dimension parallel to the direction of flow of said gas in saidstream.

15. In a process of converting initial fluid hydrocarbons into fluid hydrocarbon products by passing said initial fluid hydrocarbons through contact material in a plurality of catalyst paths, continuing such passage of hydrocarbons until deposition of a combustible contaminating deposit on said material renders the same inefficient, and regenerating the contaminated contact material by passing a combustion supporting gas therethrough; the improvement which comprises passing said gas through said contact material in the form of a plurality of streams defined to a major extent by heat exchange surfaces, each of said streams being in restricted intercommunication with at least one other of said streams adjacent thereto throughout substantially the full extent of a dimension at right angles to the direction of flow of gas in said streams.

., 16. In a process of converting initial fluid hydrocarbons into fluid hydrocarbon products by passing said initial fluid hydrocarbons through contact material in a plurality of catalyst paths, continuing such passage of hydrocarbons until deposition of a combustibl contaminating deposit on said material renders the same inefficient, and regenerating the contaminated contact material by passing a combustion supporting gas therethrough; the improvement which comprises passing said gas through said contact material in the form of a plurality of streams defined to a major extent by heat exchange surfaces, each of said streams being in restricted intercommunication with at least one other of said streams adjacent thereto throughout substantially the full extent of a dimension parallel to the direction of flow of said gas in said stream, and abstracting heat from said contact material through said heat exchange surfaces.

17. In a process of converting initial fluid hydrocarbons into fluid hydrocarbon products by passing said initial fluid hydrocarbons through contact material in a plurality of catalyst paths, continuing suchpassage of hydrocarbons until deposition of a combustible contaminating deposit on said material renders the same inefiicient, and regenerating the contaminated contact material by passing a combustion supporting gas therethrough; the improvement which comprises passing said gas through said contact material in the form of a plurality of streams defined to a major extent by heat exchange surfaces, each of said streams being in restricted intercommunication with at least one other of said streams adjacent thereto throughout substantially th full extent of a dimension at right angles to the direction of flow of gas in said streams, and abstracting heat from said contact material through said heat exchange surfaces.

18. In a process of converting initial fluid hydrocarbons into fluid hydrocarbon products by passing said initial fluid hydrocarbons through contact material in a pluralityof catalyst paths, continuing, such passage of hydrocarbons until deposition of a combustible contaminating deposit on said material renders same inefficient, and regenerating the contaminated contact ma.- terial by passing a combustion supporting gas therethrough; the improvement which comprises passing said fluid hydrocarbon through said contact material in the form of a plurality of streams defined to a major extent by heat conductive surfaces, each of said streams being in restricted intercommunication with at least one other of said streams adjacent thereto.

THOMAS P. SIMPSON JOHN W. PAYNE.

JOHN A. CROWLEY, JR.

CLARK S. TEITSWORTH. 

